Self-Catalysis Transformation of Metal-Organic Coordination Polymers.

Designing a multidimensional transformation of metal-organic coordination polymers (MOPs) is highly attractive yet very challenging. Herein, by combining the dynamicity of the coordination bond with the controllability of the chemical reaction, the concept of self-catalysis transformation of MOPs is first proposed. It uses the metal in MOPs as the catalyst to catalyze the chemical reaction of the ligand in the frameworks, simultaneously changing the coordination environment of the metal and the structure of the ligand, resulting in the controllable multidimensional transformation in the morphology and structure of MOPs. The self-catalysis transformation of MOPs can be triggered by heat or light, and crystals with various morphologies and structures can be obtained. Significantly, because the self-catalysis reaction is constraint in the framework, the products at different transformation processes are relatively stable. Monitoring and characterizing the transformation of MOPs give evidences for the exploration of the self-catalysis reaction, and a plausible transformation mechanism is proposed and proved. It can be foreseen that this novel self-catalysis transformation strategy might open up a new direction for the diverse development of MOPs and provide a powerful tool for the study of organic reaction mechanism.