A Flexible and Robust Structural Color Film Obtained by Assembly of Surface-Modified Melanin Particles.
Daiki YoshiokaKeiki KishikawaMichinari KohriPublished in: Nanomaterials (Basel, Switzerland) (2022)
In this study, core-shell-hairy-type melanin particles surface modified with a polydopamine shell layer and a polymer brush hairy layer were fabricated and assembled to readily obtain bright structural color films. The hot pressing of freeze-dried samples of melanin particles decorated with a hydrophilic, low glass transition temperature polymer brush results in films that exhibit an angle-dependent structural color due to a highly periodic microstructure, with increased regularity in the arrangement of the particle array due to the fluidity of the particles. Flexible, self-supporting, and easy-to-cut and process structural color films are obtained, and their flexibility and robustness are demonstrated using compression tests. This method of obtaining highly visible structural color films using melanin particles as a single component will have a significant impact on practical materials and applications.
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