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Electrical discharge triggers quasicrystal formation in an eolian dune.

Luca BindiMatthew A PasekChi MaJinping HuGuangming ChengNan YaoPaul D AsimowPaul J Steinhardt
Published in: Proceedings of the National Academy of Sciences of the United States of America (2022)
We report the discovery of a dodecagonal quasicrystal Mn 72.3 Si 15.6 Cr 9.7 Al 1.8 Ni 0.6 -composed of a periodic stacking of atomic planes with quasiperiodic translational order and 12-fold symmetry along the two directions perpendicular to the planes-accidentally formed by an electrical discharge event in an eolian dune in the Sand Hills near Hyannis, Nebraska, United States. The quasicrystal, coexisting with a cubic crystalline phase with composition Mn 68.9 Si 19.9 Ni 7.6 Cr 2.2 Al 1.4 , was found in a fulgurite consisting predominantly of fused and melted sand along with traces of melted conductor metal from a nearby downed power line. The fulgurite may have been created by a lightning strike that combined sand with material from downed power line or from electrical discharges from the downed power line alone. Extreme temperatures of at least 1,710 °C were reached, as indicated by the presence of SiO 2 glass in the sample. The dodecagonal quasicrystal is an example of a quasicrystal of any kind formed by electrical discharge, suggesting other places to search for quasicrystals on Earth or in space and for synthesizing them in the laboratory.
Keyphrases
  • room temperature
  • drinking water
  • metal organic framework
  • transition metal
  • ionic liquid
  • electron microscopy