Cp*Co(III)-Catalyzed C-7 C-C Coupling of Indolines with Aziridines: Merging C-H Activation and Ring Opening.

Pinaki Bhusan DeSayan AttaSourav PradhanSonbidya BanerjeeTariq A ShahTharmalingam Punniyamurthy

Published in: The Journal of organic chemistry (2020)

A Cp*Co(III)-catalyzed directing group-assisted C7 C-C coupling of indolines with aziridines has been developed by merging C-H activation and ring opening. The use of cobalt catalyst, detection of a Co(III) intermediate, and late-stage removal of the directing group are important practical features.

Keyphrases

room temperature
ionic liquid
reduced graphene oxide
metal organic framework
highly efficient
label free
electron transfer
quantum dots