Highly Active Pyrochlore-Type Praseodymium Ruthenate Electrocatalyst for Efficient Acid-Water Oxidation.

To produce directly combustible hydrogen from water, highly active, acid-resistant, and economical catalysts for oxygen evolution reaction (OER) are needed. An electrocatalyst based on praseodymium ruthenate (Pr 2 Ru 2 O 7 ) is presented here that greatly outperforms RuO 2 for acid-water oxidation. Specifically, at 10 mA cm -2 , this electrocatalyst presents a low overpotential (η) of 213 mV and markedly superior stability. Moreover, Pr 2 Ru 2 O 7 presents a significant rise in turnover frequency (TOF) and a highly intrinsic mass activity of 1618.8 A g Ru -1 (η = 300 mV), exceeding the most commonly reported acid OER catalysts. Density functional theory calculations and electronic structure study demonstrate that the Ru 4d-band center related to the longer Ru-O bond with a large radius of Pr ion in this pyrochlore is lower than that in RuO 2 , which would optimize the binding between the adsorbed oxygen species and catalytic metal sites and enhance the catalytic intrinsic activity.