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Mechanism and selectivity of photocatalyzed CO 2 reduction by a function-integrated Ru catalyst.

Ya-Qiong ZhangYing-Ying LiFeliu MaserasRong-Zhen Liao
Published in: Dalton transactions (Cambridge, England : 2003) (2022)
The phosphine-substituted Ru(II) polypyridyl complex, [Ru II -(tpy)(pqn)(MeCN)] 2+ (RuP), was disclosed to be an efficient photocatalyst for the reduction of CO 2 to CO with excellent selectivity. In this work, density functional calculations were performed to elucidate the reaction mechanism and understand the origin of selectivity. The calculations showed that RuP was first excited to the singlet excited state, followed by intersystem crossing to produce a triplet species (3RuIII(L˙-)-S), which was then reduced by the sacrificial electron donor BIH to generate a Ru II (L˙ - ) intermediate. The ligand of Ru II (L˙ - ) was further reduced to produce a Ru II (L 2- ) intermediate. The redox non-innocent nature of the tpy and pqn ligands endows the Ru center with an oxidation state of +2 after two one-electron reductions. Ru II (L 2- ) nucleophilically attacks CO 2 , in which two electrons are delivered from the ligands to CO 2 , affording a Ru II -COOH species after protonation. This is followed by the protonation of the hydroxyl moiety of Ru II -COOH, coupled with the C-O bond cleavage, resulting in the formation of Ru II -CO. Ultimately, CO is dissociated after two one-electron reductions. Protonation of Ru II (L 2- ) to generate a Ru II -hydride, a critical intermediate for the production of formate and H 2 , turns out to be kinetically less favorable, even though it is thermodynamically more favorable. This fact is due to the presence of a Ru 2+ ion in the reduced catalyst, which disfavors its protonation.
Keyphrases
  • energy transfer
  • quantum dots
  • highly efficient
  • electron transfer