Nanotribological Printing: A Nanoscale Additive Manufacturing Method.

Additive manufacturing methods are transforming the way components and devices are fabricated, which in turn is opening up completely new vistas for conceiving and designing products and engineered systems. Small-scale (submicrometer) additive manufacturing methods are largely in their infancy. While a number of methods exist, a particular challenge lies in finding methods that can produce a range of materials while obtaining sufficiently robust mechanical properties. In this paper, we describe a novel nanoscale additive manufacturing technique deemed "Nanotribological Printing" (NTP), which creates structures through tribomechanical and tribochemical surface interactions at the contact between a substrate and an atomic force microscope probe, where material pattern formation is driven by normal and shear contact stresses. The "ink" consists of nanoparticles or molecules dispersed in a carrier fluid surrounding the atomic force microscope (AFM) probe, which are entrained into the contact during sliding. Being stress-driven, patterning only occurs locally within regions which experience contact and sufficiently high stresses. Thus, imaging and measurement to characterize the morphology and properties of the deposited structures can be conducted in situ during the manufacturing process. Moreover, using local mechanical energy as the kinetic driver activating the solidification process, the method is compact and does not require application of a bias voltage or laser exposure and can be performed at ambient temperatures. We demonstrate (1) control of pattern dimensions with sub-100 nm lateral and sub-5 nm thickness control through variations in contact size and applied stress, (2) creation of amorphous, polycrystalline, and nanocomposite structures including sequential multimaterial deposition, and (3) formation of manufactured structures which exhibit mechanical properties approaching those of bulk counterparts. The ability to create nanoscale patterns using standard AFM cantilever probes and operation modes (contact mode scanning in fluid) with commercial AFM instruments, independent of substrate, establishes NTP as a versatile and easily accessible method for nanoscale additive manufacturing.