Air-stable Perylene Diimide Trimer Material for n-type Organic Electrochemical Transistors.

We report a new method to make air-stable n-type organic mixed ionic-electronic conductor (OMIEC) films for organic electrochemical transistors (OECTs) using a solution-processable small molecule helical perylene diimide trimer, hPDI[3]-C 11 . Alkyl side chains were attached to the conjugated core for processability and film making, which were then cleaved via thermal annealing. After the sidechains were removed, the hPDI[3] film becomes less hydrophobic, more ordered, and has a deeper lowest unoccupied molecular orbital (LUMO). These features provide improved ionic transport, greater electronic mobility, and increased stability in air and in aqueous solution. Subsequently, we use hPDI[3]-H as the active material in OECTs and demonstrate a device with a transconductance of 44 mS, volumetric capacitance of ∼250 F/cm 3 , µC * value of 1 F/cmVs, and excellent stability (> 5 weeks). As proof of their practical applications, we utilize a hPDI[3]-H-based OECTs as a glucose sensor and electrochemical inverter. The approach of side chain removal after film formation charts a path to a wide range of molecular semiconductors to be used as stable, mixed ionic-electronic conductors. This article is protected by copyright. All rights reserved.