Mechanical Strength and Conductivity of Cementitious Composites with Multiwalled Carbon Nanotubes: To Functionalize or Not?

The incorporation of carbon nanotubes into cementitious composites increases their compressive and flexural strength, as well as their electrical and thermal conductivity. Multiwalled carbon nanotubes (MWCNTs) covalently functionalized with hydroxyl and carboxyl moieties are thought to offer superior performance over bare nanotubes, based on the chemistry of cement binder and nanotubes. Anionic carboxylate can bind to cationic calcium in the hydration products, while hydroxyl groups participate in hydrogen bonding to anionic and nonionic oxygen atoms. Results in the literature for mechanical properties vary widely for both bare and modified filler, so any added benefits with functionalization are not clearly evident. This mini-review seeks to resolve the issue using an analysis of reports where direct comparisons of cementitious composites with plain and functionalized nanotubes were made at the same concentrations, with the same methods of preparation and under the same conditions of testing. A focus on observations related to the mechanisms underlying the enhancement of mechanical strength and conductivity helps to clarify the benefits of using functionalized MWCNTs.