Luminescent magnesium complexes with intra- and inter-ligand charge transfer.

Rohit KumarSanjukta PaharJoy ChatterjeeSoumya Ranjan DashRajesh G Gonnade Kumar Vanka Sakya S Sen

Published in: Chemical communications (Cambridge, England) (2022)

Herein, we report two 2,2'-pyridylpyrrolide (PyPyrH) ligand supported magnesium complexes (1 and 2), which demonstrate bright luminescence with a quantum yield of 22% and 14% in the solid state, respectively. Theoretical calculations reveal that their emissive properties originate from the intra- and inter-ligand charge transfer.

Keyphrases

solid state
molecular dynamics
energy transfer
quantum dots
light emitting
density functional theory
molecular dynamics simulations
single cell
gene expression
monte carlo
sensitive detection