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Rh(I) and Organo-Rh(III) Complexes of meso -Triarylbiphenylcorrole.

Sangya ChitranshiB AdinarayanaMainak DasSebastian AnilaCherumuttathu H SureshA Srinivasan
Published in: Inorganic chemistry (2022)
Rhodium complexes of biphenylcorrole are reported, and the molecular structures of the complexes are unambiguously confirmed by single-crystal X-ray analysis. The adj -CCNN core of the dicarbacorrole efficiently stabilizes a rhodium metal ion in its two different oxidation states. It is pertinent to point out that the Rh(I) metal complex attains square-planar geometry while organo-Rh(III) forms an octahedral complex. Furthermore, density functional theory studies corroborate the experimental findings.
Keyphrases
  • density functional theory
  • high resolution
  • molecular dynamics
  • computed tomography
  • magnetic resonance
  • mass spectrometry
  • contrast enhanced