Generation and Characterization of the First Persistent Platinum(I)-Centered Radical.

Yosi KratishArseni KostenkoAlexander KaushanskyBoris TumanskiiDmitry Bravo-ZhivotovskiiYitzhak Apeloig

Published in: Angewandte Chemie (International ed. in English) (2018)

The first persistent platinum(I)-centered radical was generated by homolytic cleavage of a Pt-HgSiR3 bond of a mercury-substituted platinum(II) complex. The PtI radical was characterized by EPR spectroscopy, chemical trapping experiments, and density functional theory (DFT) calculations.

Keyphrases

density functional theory
molecular dynamics
molecular docking
high resolution
single molecule
molecular dynamics simulations
transcription factor
mass spectrometry
electron transfer