A ferric guest inside a spin crossover ferrous helicate.

Leoní A BarriosRosa DiegoMohanad D Darawsheh Jesús I Martínez Olivier Roubeau Guillem Aromí

Published in: Chemical communications (Cambridge, England) (2022)

A designed dimetallic Fe(II) helicate made with biphenylene-bridged bispyrazolylpyridine ligands and exhibiting a process of spin crossover at temperatures above ambient is shown to encapsulate an S = 5/2 tris-oxalato Fe(III) ion. The spin relaxation dynamics of this guest are strongly reduced upon encapsulation.

Keyphrases

single molecule
room temperature
density functional theory
open label
transition metal
air pollution
placebo controlled
double blind
metal organic framework
water soluble
study protocol