In Situ Control of Crystallinity of 3D Colloidal Crystals by Tuning the Growth Kinetics of Nanoparticle Building Blocks.

Colloidal crystals (CCs) constructed from inorganic nanoparticle (NP) building blocks exhibit properties that cannot be realized from isolated NPs or corresponding bulk counterparts. Because the arrangement of NPs in CCs is crucial in the CC's collective properties, development of a procedure to modulate the assembly of NP constituents is important. We demonstrate rapid formation of nickel (phosphide) CCs with tunable crystallinity through van der Waals force-driven spontaneous self-assembly of NPs in a facile one-pot colloidal synthesis. The quantity of size-regulating reagent (tri- n -octylphosphine) modulates the assembly of NPs from ordered close-packed to a disordered configuration in CCs. Synchrotron-based in situ small-angle X-ray scattering revealed that the size uniformity of the NPs determines the crystallinity of CCs, indicating the importance of regulating the growth kinetics of NPs during the synthesis. Our work will be useful for universal scalable preparation of CCs from a variety of materials and structures, with tunable concerted properties.