A dual-mode sensor based on colorimetric and Tyndall effect of gold nanoparticles for ultra-sensitive detection of Hg 2 .

Mercury ion (Hg 2+ ) is the most widespread and highly toxic environmental pollutant, which exerts numerous adverse effects on environmental and human health. There is an urgent need to develop a convenient method for detecting Hg 2+ . Herein, a novel dual-mode sensor based on colorimetric and Tyndall effect of gold nanoparticles was developed for ultra-sensitive determination of Hg 2+ . In this strategy, a polyA-modified Au probe with high uniformity was assembled successfully. Both modes were based on Hg 2+ -induced aggregation of the probes. Hg 2+ was reflected according to the color variations of solution and the Tyndall effect of Au reporter. With the aid of a laser pointer, the Tyndall mode demonstrated about 615-fold improvement on sensitivity compared with the colorimetry way. Taking advantages of low cost and convenient assembly of polyA-based Au probe and the combination of colorimetry and Tyndall effect, our strategy determined the Hg 2+ with high sensitivity and wide range. By changing probes or nanoparticles, the proposed strategy is expected to be a universal platform for detecting other analytes in environmental and even biological samples. A novel dual-mode sensor based on colorimetric and tyndall effect of gold nanoparticles for ultra-sensitive determination of Hg2+ was exploited.