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Ship in bottle synthesis of yolk-shell MnS@hollow carbon spheres for sodium storage.

Jianyun ZhaoYuxiao YangChuan JiangNawab Ali KhanXin JiaHongyang ZhaoShujiang Ding
Published in: Nanotechnology (2021)
Yolk-shell structure can effectively alleviate the volume change of electrodes during electrochemical charge/discharge. In this paper, we provide a new ship in bottle strategy to synthesize MnS@C sodium ion battery anode with yolk-shell nanostructure. The obtained yolk-shell structures were uniform spheres. The space between the carbon shell and MnS core allows the volume change of MnS without deforming the carbon shell or damaging the solid electrolyte interface film formed on the outer surface. The MnS@C yolk-shell structure showed stable cycle stability (336 mAh g-1capacity after 200 cycles at 0.5 A g-1current density).
Keyphrases
  • reduced graphene oxide
  • ionic liquid
  • gold nanoparticles
  • molecularly imprinted
  • high resolution
  • ion batteries
  • mass spectrometry
  • room temperature