Metal-mediated tunability of MOF-based optical modulators.

Nikita K Kulachenkov Bogdan OrliogloEugene S VasilyevSvyatoslav A PovarovAlexander M AgafontsevSemyon BachininSergei A ShipilovskikhArtem LunevDenis G Samsonenko Vladimir Petrovich Fedin Konstantin Aleksandrovich Kovalenko Valentin A Milichko

Published in: Chemical communications (Cambridge, England) (2023)

We report on the design of 1D MOFs based on a nopinane-annelated organic ligand and Co(II) or Ni(II), the variation of which allows tuning the optical modulation bandwidth. Structural and time-resolved analysis revealed the optical modulation mechanism, the rates and its endurance, thereby enriching the list of sustainable MOFs for tunable optical modulators.

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