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Long-Range Chiral Induction by a Fully Noncovalent Approach in Supramolecular Porphyrin-Calixarene Assemblies.

Massimiliano GaetaGiuseppe SortinoRosalba RandazzoIlenia PisagattiAnna NottiMaria Elena FragalàMelchiorre F ParisiAlessandro D'UrsoRoberto Purrello
Published in: Chemistry (Weinheim an der Bergstrasse, Germany) (2020)
The hierarchical assembly, in aqueous solution, of a new multi-metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favorable and fully noncovalent long-range electronic communication.
Keyphrases
  • aqueous solution
  • energy transfer
  • photodynamic therapy
  • electron transfer
  • metal organic framework
  • quantum dots
  • water soluble
  • crispr cas
  • ionic liquid
  • capillary electrophoresis