Computational Screening of Metal⁻Organic Framework Membranes for the Separation of 15 Gas Mixtures.
Wenyuan YangHong LiangFeng PengZili LiuJie LiuZhiwei QiaoPublished in: Nanomaterials (Basel, Switzerland) (2019)
The Monte Carlo and molecular dynamics simulations are employed to screen the separation performance of 6013 computation-ready, experimental metal⁻organic framework membranes (CoRE-MOFMs) for 15 binary gas mixtures. After the univariate analysis, principal component analysis is used to reduce 44 performance metrics of 15 mixtures to a 10-dimension set. Then, four machine learning algorithms (decision tree, random forest, support vector machine, and back propagation neural network) are combined with k times repeated k-fold cross-validation to predict and analyze the relationships between six structural feature descriptors and 10 principal components. Based on the linear correlation value R and the root mean square error predicted by the machine learning algorithm, the random forest algorithm is the most suitable for the prediction of the separation performance of CoRE-MOFMs. One descriptor, pore limiting diameter, possesses the highest weight importance for each principal component index. Finally, the 30 best CoRE-MOFMs for each binary gas mixture are screened out. The high-throughput computational screening and the microanalysis of high-dimensional performance metrics can provide guidance for experimental research through the relationships between the multi-structure variables and multi-performance variables.
Keyphrases
- metal organic framework
- machine learning
- neural network
- ionic liquid
- room temperature
- molecular dynamics simulations
- high throughput
- deep learning
- artificial intelligence
- monte carlo
- liquid chromatography
- climate change
- big data
- molecular docking
- mass spectrometry
- carbon dioxide
- physical activity
- body mass index
- weight loss
- optical coherence tomography