Charge-assisted phosph(v)azane anion receptors.

Alex J PlajerSanha LeeAndrew D Bond Jonathan M Goodman Dominic S Wright

Published in: Dalton transactions (Cambridge, England : 2003) (2020)

Coordination of Cu(i) or Pd(ii) to seleno-cyclodiphosph(v)azanes of the type [RNH(Se)P(μ-NtBu)]2 results in positively charged anion receptor units which have increased anion affinity over the neutral seleno-phosph(v)azanes, due to the increase in electrostatic interactions between the receptor and the guest anions. The same effect is produced by replacement of one of the P[double bond, length as m-dash]Se units by a P-Me+ unit.

Keyphrases

ionic liquid
binding protein
molecular dynamics simulations
solar cells
water soluble