Anionic Porous Zn-Metalated Porphyrin Metal-Organic Framework with PtS Topology for Gas-Phase Photocatalytic CO 2 Reduction.
Jian-Hua QinZhi XiaoPeng XuZhi-Hua LiXiaoyan LuXiao-Gang YangWeiwei LuLu-Fang MaDong-Sheng LiPublished in: Inorganic chemistry (2022)
Presented here are the synthesis and gas-phase photocatalytic CO 2 reduction of an anionic porous Zn-metalated porphyrin metal-organic framework (MOF) induced by an ionic liquid. The desired CO 2 affinity and deep conduction band position of the MOF catalyst provide strong kinetic and thermodynamic advantages for photocatalytic CO 2 to CH 4 conversion with high selectivity (∼70%) in H 2 O vapor.