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Do 2-coordinate iodine(I) and silver(I) complexes form nucleophilic iodonium interactions (NIIs) in solution?

Scott WilcoxDaniel SethioJas S WardAntonio FronteraRoland LindhKari T RissanenMáté Erdélyi
Published in: Chemical communications (Cambridge, England) (2022)
The interaction of a [bis(pyridine)iodine(I)] + cation with a [bis(pyridine)silver(I)] + cation, in which an iodonium ion acts as a nucleophile by transferring electron density to the silver(I) cation, is reinvestigated herein. No measurable interaction is observed between the cationic species in solution by NMR; DFT reveals that if there is an attractive interaction between these complexes in solution, it is dominantly the π-π interaction of pyridines.
Keyphrases
  • ionic liquid
  • gold nanoparticles
  • solid state
  • silver nanoparticles
  • magnetic resonance
  • high resolution
  • computed tomography
  • magnetic resonance imaging
  • mass spectrometry
  • dual energy
  • molecular dynamics