Visible-light-catalyzed C-H arylation of (hetero)arenes via arylselenonium salts.

A novel photo-induced C-H arylation of (hetero)arenes has been developed. Aryl selenonium salts as an aryl source led to the arylation of aromatic (hetero)cyclic compounds via C-Se bond activation under blue LED irradiation. The method simply utilizes the safe and clean energy source and yields a range of site-selective biphenyl or bi-heterocyclic products in medium to good yields. Furthermore, the borylation and Sonogashira coupling of aryl selenonium salts proceed in good yields as well. From the results, it is shown that selenonium salts are more reactive than sulfonium salts.