Aminomethylation of Fullerene C60 with N,N',N″-Triaryl- or N,N',N″-Trihetaryl-1,3,5-perhydrotriazines in the Presence of EtMgBr and Ti(Oi-Pr)4.

Airat R TuktarovArtur A KhuzinArtur R TulyabaevNatal'ya R Popod'koUsein M Dzhemilev

Published in: The Journal of organic chemistry (2017)

A new method for the functionalization of fullerenes based on the reaction between in situ generated aryl- or hetaryl-containing 1,3,5-perhydrotriazines and EtMgBr in the presence of Ti(Oi-Pr)4 has been developed. The cleavage of the triazine ring under previously developed conditions1-6 results in the formation of aminomethylated derivatives of fullerene C60 with high yields (80-90%) and selectivity (∼90%).

Keyphrases

solar cells
dna binding
mass spectrometry
transcription factor
structural basis