Exfoliation of a two-dimensional cationic inorganic network as a new paradigm for high-capacity CrVI-anion capture.
Huimin YangHonghan FeiPublished in: Chemical communications (Cambridge, England) (2017)
We have discovered a rare example of a non-LDH cationic inorganic layered material [Cu4(OH)6][O3S(CH2)4SO3]. Its in situ exfoliation achieves record high adsorption capacities for chromate and dichromate. This phenomenon is ascribed to the combination of the strong host-anion electrostatic interactions and the high surface area of our cuprate material, which overcomes the memory effect problem of LDHs. Moreover, our material also selectively captures CrVI with a negligible decrease in capacity when non-toxic, monovalent anions are present.