A Metal-Organic Framework with a Pore Size/Shape Suitable for Strong Binding and Close Packing of Methane.
Jiao-Min LinChun-Ting HeYan LiuPei-Qin LiaoDong-Dong ZhouJie-Peng ZhangXiao-Ming ChenPublished in: Angewandte Chemie (International ed. in English) (2016)
Much effort has been devoted to develop new porous structures for methane storage. We report a new porous coordination framework showing exceptional methane uptakes (e.g. 263 v/v at 298 K and 65 bar) and adsorption enthalpies (21.6 kJ mol(-1)) as high as current record holders functionalized by open metal sites. Computational simulations demonstrated that the hierarchical pore structure consisting of single-wall nanocages has suitable sizes/shapes and organic binding sites to enforce not only strong host-methane and methane-methane interactions but also dense packing of methane molecules.