Ag 2 S-Ag 2 O-Ag/poly-2-aminobenzene-1-thiol Nanocomposite as a Promising Two-Electrode Symmetric Supercapacitor: Tested in Acidic and Basic Mediums.

A Ag 2 S-Ag 2 O-Ag/poly-2-aminobenzene-1-thiol (P2ABT) nanocomposite was prepared using the photopolymerization reaction using AgNO 3 as an oxidant. The size of the nanocomposite was about 40 nm, in which the morphology was confirmed using TEM and SEM analyses. The functional groups of Ag 2 S-Ag 2 O-Ag/P2ABT were confirmed using FTIR; also, XRD confirmed the inorganic Ag 2 S, Ag, and Ag 2 O formation. This nanocomposite has great performance in supercapacitor applications, with it tested in acidic (1.0 M HCl) and basic mediums (1.0 M NaOH). This pseudo-capacitor has great performance that appeared through the charge time in an acid medium in comparison to the basic medium with values of 118 s and 103 s, correspondingly. The cyclic voltammetry (CV) analysis further confirmed the excellent performance of the supercapacitor material, as indicated by the large area under the cyclic curve. The specific capacitance (C S ) and energy density (E) values (at 0.3 A/g) were 92.5 and 44.4 F/g and 5.0 and 2.52 W·h·Kg -1 in the acidic and basic mediums, correspondingly. The charge transfer was studied through a Nyquist plot, and the produced R s values were 4.9 and 6.2 Ω, respectively. Building on these findings, our objective is to make a significant contribution to the progress of supercapacitor technology through a prototype design soon.