Partially fluorinated poly(arylene-alkane)s containing cobaltocenium for alkaline-stable anion exchange membranes.

Run ZhangXiaoyu ZhaoWenhao LiHuidong Qian Hui Yang

Published in: Chemical communications (Cambridge, England) (2023)

Alkali-resistant metal-based cationic polyelectrolytes are designed as anion exchange membranes. After grafting aminocobaltocene hexafluorophosphates onto partially fluorinated ether-free poly(arylene-alkane)s via a simple nucleophilic substitution reaction, the membrane exhibits excellent chemical, thermal and mechanical stability, high hydroxide conductivity, as well as durability of single cells for 400 h.

Keyphrases

ionic liquid
induced apoptosis
cell cycle arrest
endoplasmic reticulum stress
oxidative stress
cell death
pi k akt
electron transfer