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An extended-gate-type organic transistor for monitoring the Menschutkin reaction of tetrazole at a solid-liquid interface.

Yui SasakiKohei OhshiroXiaojun LyuTakayuki KawashimaMasao KamikoHikaru TanakaAkari YamagamiYoshinori UenoTsuyoshi Minami
Published in: Chemical communications (Cambridge, England) (2024)
We herein propose an approach to visualize the Menschutkin reaction at an interface between a self-assembled monolayer with nucleophilic properties and water containing alkyl halides. An organic field-effect transistor functionalized with a nucleophilic monolayer has detected in situ alkylation depending on differences in the leaving group ability and the bulkiness of electrophilic alkyls.
Keyphrases
  • ionic liquid
  • water soluble
  • quantum dots
  • electron transfer
  • molecularly imprinted
  • visible light