Influence of a neighbouring Cu centre on electro- and photocatalytic CO 2 reduction by Fe-Mabiq.
Kerstin RickmeyerMatthias HuberCorinna R HessPublished in: Chemical communications (Cambridge, England) (2024)
Electrocatalytic and photocatalytic CO 2 reduction by a heterobimetallic Cu/Fe-Mabiq complex were examined and compared to the monometallic [Fe(Mabiq)] + . The neighbouring Cu-Xantphos unit leads to marked changes in the electrocatalytic mechanism and enhanced photocatalytic performance.