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Coordination-induced reductive elimination from a titanium(IV) complex.

Paul FritscheLucia GeyerCorinna CzernetzkiGabriele Hierlmeier
Published in: Chemical communications (Cambridge, England) (2024)
Diamidopyridine-supported titanium dibenzyl complexes undergo coordination-induced C-C reductive elimination upon addition of alkynes and quantitative formation of titanacyclopentadienes. The distinct radical mechanism of this reductive mechanism gives new insights into C-C bond formation with titanium.
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