Room-Temperature Synthesis of a Hollow Microporous Organic Polymer Bearing Activated Alkyne IR Probes for Nonradical Thiol-yne Click-Based Post-Functionalization.
Jong In ParkJune Young JangYoon-Joo KoSang Moon LeeHae Jin KimHye-Young JangKyoung Chul KoSeung Uk SonPublished in: Chemistry, an Asian journal (2021)
This work shows that hollow microporous organic polymer (H-MOP-A) with activated internal alkynes as IR probes can be prepared by template synthesis based on acyl Sonogashira-Hagihara coupling at room temperature. The H-MOP-A is a versatile platform in the main chain PSM based on nonradical thiol-yne click reaction. Moreover, an IR peak of internal alkynes in the H-MOP-A is very intense and could be utilized in the monitoring of thiol-yne click-based main chain PSM. The functionalized H-MOP-A with carboxylic acids (H-MOP-CA) showed efficient adsorption toward Ag+ ions. The resultant H-MOP-CA-Ag showed excellent performance in the CO2 fixation to α-alkylidene cyclic compounds.
Keyphrases
- room temperature
- quantum dots
- ionic liquid
- molecularly imprinted
- small molecule
- highly efficient
- living cells
- single molecule
- minimally invasive
- water soluble
- high throughput
- high resolution
- aqueous solution
- mass spectrometry
- simultaneous determination
- protein kinase
- liquid chromatography
- solid phase extraction
- visible light