Layer-by-Layer Organic Photovoltaic Solar Cells Using a Solution-Processed Silicon Phthalocyanine Non-Fullerene Acceptor.

Silicon phthalocyanines (SiPcs) are promising, inexpensive, and easy to synthesize non-fullerene acceptor (NFA) candidates for all-solution sequentially processed layer-by-layer (LbL) organic photovoltaic (OPV) devices. Here, we report the use of bis(tri- n -butylsilyl oxide) SiPc ((3BS) 2 -SiPc) paired with poly(3-hexylthiophene) (P3HT) and poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)-benzo[1,2-b:4,5-b']dithiophene))- alt -(5,5-(1',3'-di-2-thienyl-5',7'-bis(2-ethylhexyl)benzo[1',2'-c:4',5'-c']dithiophene-4,8-dione))] (PBDB-T) donors in an LbL OPV structure. Using a direct architecture, P3HT/(3BS) 2 -SiPc LbL devices show power conversion efficiencies (PCEs) up to 3.0%, which is comparable or better than the corresponding bulk heterojunction (BHJ) devices with either (3BS) 2 -SiPc or PC 61 BM. PBDB-T/(3BS) 2 -SiPc LbL devices resulted in PCEs up to 3.3%, with an impressive open-circuit voltage ( V oc ) as high as 1.06 V, which is among the highest V oc obtained employing the LbL approach. We also compared devices incorporating vanadium oxide (VOx) or poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) as a hole transporting layer and found that VOx modified the donor layer morphology and led to improved V oc . Probing the composition as a function of film layer depths revealed a similar distribution of active material for both BHJ and LbL structures when using (3BS) 2 -SiPc as an NFA. These findings suggest that (3BS) 2 -SiPc is a promising NFA that can be processed using the LbL technique, an inherently easier fabrication methodology for large-area production of OPVs.