Water Increases the Faradaic Selectivity of Li-Mediated Nitrogen Reduction.

The lithium-mediated system catalyzes nitrogen to ammonia under ambient conditions. Herein we discover that trace amount of water as an electrolyte additive-in contrast to prior reports from the literature-can effect a dramatic improvement in the Faradaic selectivity of N 2 reduction to NH 3 . We report that an optimal water concentration of 35.9 mM and LiClO 4 salt concentration of 0.8 M allows a Faradaic efficiency up to 27.9 ± 2.5% at ambient pressure. We attribute the increase in Faradaic efficiency to the incorporation of Li 2 O in the solid electrolyte interphase, as suggested by our X-ray photoelectron spectroscopy measurements. Our results highlight the extreme sensitivity of lithium-mediated N 2 reduction to small changes in the experimental conditions.