Grafted iron(iii) ions significantly enhance NO 2 oxidation rate and selectivity of TiO 2 for photocatalytic NO x abatement.

Semiconductor photocatalysis could be an effective means to combat nitrogen oxides (NO x ) based air pollution through mineralisation of NO x to nitrate. However, most of the typically TiO 2 -based catalysts employed show a much higher reactivity towards NO than NO 2 , leading to an accumulation of this unwanted and toxic intermediate. By grafting the photocatalyst with small amounts (≤0.1 at%) of isolated iron(iii) ions, the reactivity towards NO 2 is increased by the factor of 9, bringing it up to par with the NO-reactivity and alleviating the problem with intermediate accumulation. Consequently, the observed selectivity of the reaction is dramatically increased from less than 40% to more than 90%. The paper also discusses possible mechanisms for this very beneficial behavior.