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A lithium-scandium sulfate with second-harmonic generation response and deep-ultraviolet transparency.

Zi-Long GengHong-Xin TangRui-Biao FuZu-Ju MaXin-Tao Wu
Published in: Dalton transactions (Cambridge, England : 2003) (2023)
A new beryllium-free deep-UV transparent NLO crystal Li(H 2 O) 2 Sc(SO 4 ) 2 features a two-dimensional [Sc(SO 4 ) 2 ] framework consisting of twisted [Sc 3 S 4 O 9 ] units decorated by [LiO 2 (H 2 O) 2 ] groups into a unique layer. Remarkably, Li(H 2 O) 2 Sc(SO 4 ) 2 exhibits a phase-matching SHG response of 0.7 × KDP and a deep-UV cutoff edge below 190 nm.
Keyphrases
  • solid state
  • ion batteries
  • photodynamic therapy
  • quantum dots
  • light emitting
  • gold nanoparticles
  • reduced graphene oxide