Pd-Catalyzed Dearomative Allylation of Benzyl Phosphates.

Masaaki KomatsudaKei Muto Junichiro Yamaguchi

Published in: Organic letters (2018)

Dearomative C-C bond formation of benzyl phosphates has been developed. In the presence of a palladium/PAr3 catalyst, benzyl phosphates reacted with allyl borates to generate the allylated product in a dearomative fashion. The resulting dearomatized molecules were successfully derivatized by Simmons-Smith cyclopropanation and oxidation.

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