Metalloligand-based coordination polymer embedding the nitrosyl ruthenium complex for photoactive materials with bound nitric oxide.
Vasily VorobyevAnastasia M CheplakovaElena D StolyarovaVladislav Yu KomarovGennadiy A KostinPublished in: Dalton transactions (Cambridge, England : 2003) (2022)
The stability of a photoactivated isonitrosyl state was boosted by confining a pre-designed bicarboxylate ligand with a ruthenium nitrosyl fragment in a 2D metal-organic framework. The novel Zn/Ru-based MOF, {Zn[RuNO(H 2 O)(inic) 2 (OH) 2 ] 2 }·12H 2 O (inic = isonicotinate), was obtained with enhanced isonitrosyl stability by 30 K (up to 200 K) compared to the related ruthenium-only complex.