Promotion of the Co 3 O 4 /TiO 2 Interface on Catalytic Decomposition of Ammonium Perchlorate.

Supports can widely affect or even dominate the catalytic activity and selectivity of nanoparticles because atomic geometry and electronic structures of active sites can be regulated, especially at the interface of nanoparticles and supports. However, the underlying mechanisms of most systems are still not fully understood yet. Herein, we construct the interface of Co 3 O 4 /TiO 2 to boost ammonium perchlorate (AP) catalytic decomposition. This catalyst shows enhanced catalytic performance. With the addition of 2 wt % Co 3 O 4 /TiO 2 catalysts, AP decomposition peak temperature decreases from 435.7 to 295.0 °C and activation energy decreases from 211.5 to 137.7 kJ mol -1 . By combining experimental and theoretical studies, we find that Co 3 O 4 nanoparticles can be strongly anchored onto TiO 2 supports accompanied by charge transfer. Moreover, at the interfaces in the Co 3 O 4 /TiO 2 nanostructure, NH 3 adsorption can be enhanced through hydrogen bonds. Our research studies provide new insights into the promotion effects of the nanoparticle/support system on the AP decomposition process and inspire the design of efficient catalysts.