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Nitroso-azomethine(ene) reaction enabled annulations of nitrosoarenes, azomethines and alkenes.

Anisha PurkaitSurya Veer Singh PalKaushik SoniKalishankar BhattacharyyaChandan K Jana
Published in: Chemical communications (Cambridge, England) (2024)
An unprecedented example of a nitroso-azomethine(ene) reaction is reported. Nitroso-azomethine(ene) reaction-mediated unprecedented annulation of nitrosoarenes, azomethines, and alkenes to furnish arylquinolines via arene functionalization of nitrosoarene has been developed. DFT studies provided mechanistic insights into the newly developed nitroso-azomethine(ene) reaction.
Keyphrases
  • electron transfer