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A physically realizable molecular motor driven by the Landauer blowtorch effect.

Riley J PrestonDaniel S Kosov
Published in: The Journal of chemical physics (2023)
We propose a model for a molecular motor in a molecular electronic junction driven by a natural manifestation of Landauer's blowtorch effect. The effect emerges via the interplay of electronic friction and diffusion coefficients, each calculated quantum mechanically using nonequilibrium Green's functions, within a semiclassical Langevin description of the rotational dynamics. The motor functionality is analyzed through numerical simulations where the rotations exhibit a directional preference according to the intrinsic geometry of the molecular configuration. The proposed mechanism for motor function is expected to be ubiquitous for a range of molecular geometries beyond the one examined here.
Keyphrases
  • molecular dynamics