A versatile platform for graphene nanoribbon synthesis, electronic decoupling, and spin polarized measurements.

The on-surface synthesis of nano-graphenes has led the charge in prototyping structures with perspectives beyond silicon-based technology. Following reports of open-shell systems in graphene-nanoribbons (GNRs), a flurry of research activity was directed at investigating their magnetic properties with a keen eye for spintronic applications. Although the synthesis of nano-graphenes is usually carried out on Au(111), the substrate is difficult to use for electronic decoupling and spin-polarized measurements. Using a binary alloy Cu 3 Au(111), we show possibilities for gold-like on-surface synthesis compatible with spin polarization and electronic decoupling known from copper. We prepare copper oxide layers, demonstrate the synthesis of GNRs, and grow thermally stable magnetic Co islands. We functionalize the tip of a scanning tunneling microscope with carbon-monoxide, nickelocene, or attach Co clusters for high-resolution imaging, magnetic sensing, or spin-polarized measurements. This versatile platform will be a valuable tool in the advanced study of magnetic nano-graphenes.