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Structural Phase Transition and In-Situ Energy Storage Pathway in Nonpolar Materials: A Review.

Xian-Kui WeiRafal E Dunin-BorkowskiJoachim Mayer
Published in: Materials (Basel, Switzerland) (2021)
Benefitting from exceptional energy storage performance, dielectric-based capacitors are playing increasingly important roles in advanced electronics and high-power electrical systems. Nevertheless, a series of unresolved structural puzzles represent obstacles to further improving the energy storage performance. Compared with ferroelectrics and linear dielectrics, antiferroelectric materials have unique advantages in unlocking these puzzles due to the inherent coupling of structural transitions with the energy storage process. In this review, we summarize the most recent studies about in-situ structural phase transitions in PbZrO 3 -based and NaNbO 3 -based systems. In the context of the ultrahigh energy storage density of SrTiO 3 -based capacitors, we highlight the necessity of extending the concept of antiferroelectric-to-ferroelectric (AFE-to-FE) transition to broader antiferrodistortive-to-ferrodistortive (AFD-to-FD) transition for materials that are simultaneously ferroelastic. Combining discussion of the factors driving ferroelectricity, electric-field-driven metal-to-insulator transition in a (La 1-x Sr x )MnO 3 electrode is emphasized to determine the role of ionic migration in improving the storage performance. We believe that this review, aiming at depicting a clearer structure-property relationship, will be of benefit for researchers who wish to carry out cutting-edge structure and energy storage exploration.
Keyphrases
  • ionic liquid