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Decarboxylative Hydroxylation of Benzoic Acids.

Wanqi SuPeng XuTobias Ritter
Published in: Angewandte Chemie (International ed. in English) (2021)
Herein, we report the first decarboxylative hydroxylation to synthesize phenols from benzoic acids at 35 °C via photoinduced ligand-to-metal charge transfer (LMCT)-enabled radical decarboxylative carbometalation. The aromatic decarboxylative hydroxylation is synthetically promising due to its mild conditions, broad substrate scope, and late-stage applications.
Keyphrases
  • visible light
  • amino acid