A novel supramolecular Zn(ii)-metallogel: an efficient microelectronic semiconducting device application.
Kripasindhu KarmakarArka DeySubhendu DhibarRajib SahuSubham BhattacharjeePriya KarmakarPriyajit ChatterjeeAniruddha MondalBidyut SahaPublished in: RSC advances (2023)
A unique strategy for the synthesis of a supramolecular metallogel employing zinc ions and adipic acid in DMF medium has been established at room temperature. Rheological analysis was used to investigate the mechanical characteristics of the supramolecular Zn(ii)-metallogel. Field emission scanning electron microscopy and transmission electron microscopy were used to analyse the hexagonal shape morphological features of the Zn(ii)-metallogel. Interestingly, the electrical conductivity is observed in the electronic device with Zn(ii)-metallogel based metal-semiconductor (MS) junctions. All aspects of the metallogel's electrical properties were investigated. The electrical conductivity of the metallogel-based thin film device was 7.38 × 10 -5 S m -1 . The synthesised Zn(ii)-metallogel based device was investigated for its semi-conductive properties, such as its Schottky barrier diode nature.