Tert-butyl peroxy-3,5,5-trimethylhexanoate (TBPTMH), a liquid ester organic peroxide, is commonly used as an initiator for polymerization reactions. During the production process, TBPTMH may be exposed to acids and alkali, which may have different effects on its thermal hazard, so it is necessary to carry out a study on the thermal hazard of TBPTMH mixed with acids and alkali. In this paper, the effects of H 2 SO 4 and NaOH on the thermal decomposition of TBPTMH were investigated by differential scanning calorimetry (DSC) and adiabatic calorimetry (Phi-TEC II). The "kinetic triple factors" were calculated by thermodynamic analysis. The results show that the three E a are 132.49, 116.36, and 118.24 kJ/mol, respectively; thus, the addition of H 2 SO 4 and NaOH increased the thermal hazard of TBPTMH. In addition, the characteristic parameters (time to maximum rate under adiabatic conditions, self-accelerated decomposition temperature) of its thermal decomposition were determined, and the control temperature (45, 40, and 40 °C) of TBPTMH under the action of acid-alkali were further received. This work is expected to provide some guidance for the safe storage, handling, production, and transportation of TBPTMH in the process industry.
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