Accelerated C2H2/CO2 Separation by a Se-Functionalized Porous Coordination Polymer with Low Binding Energy.

High-quality pure acetylene (C2H2) is a kind of crucial starting material for various value-added products. However, selective capture of C2H2 from the main impurity of CO2 via porous absorbents is a great challenge, as they possess extremely similar kinetic diameters and boiling points, as well as the explosive and reactive properties of C2H2. Herein, we report a porous coordination polymer (PCP), (NTU-55), which assembled from the coordination between a Cu dimer and a newly designed ligand with a nonmetal selenium (Se) site. Static single-component adsorption and dynamic breakthrough experiments reveal that desolvated NTU-55 can completely adsorb C2H2 from the C2H2/CO2 mixture (1/4, v/v) at 298 K, along with higher C2H2 capacity and much lower binding energy. The origin of this separation, as comprehensively revealed by density functional theory (DFT) calculations, is derived from the interaction discriminatory of C2H2 and CO2 toward accessible Se and Cu adsorption sites. To the best of our knowledge, this is the first time to find the positive effect of nonmetal Se sites for selective C2H2 capture.