Functionalized GO Membranes for Efficient Separation of Acid Gases from Natural Gas: A Computational Mechanistic Understanding.
Quan LiuZhonglian YangGongping LiuLonglong SunRong XuJing ZhongPublished in: Membranes (2022)
Membrane separation technology is applied in natural gas processing, while a high-performance membrane is highly in demand. This paper considers the bright future of functionalized graphene oxide (GO) membranes in acid gas removal from natural gas. By molecular simulations, the adsorption and diffusion behaviors of several unary gases (N 2 , CH 4 , CO 2 , H 2 S, and SO 2 ) are explored in the 1,4-phenylenediamine-2-sulfonate (PDASA)-doped GO channels. Molecular insights show that the multilayer adsorption of acid gases evaluates well by the Redlich-Peterson model. A tiny amount of PDASA promotes the solubility coefficient of CO 2 and H 2 S, respectively, up to 4.5 and 5.3 mmol·g -1 ·kPa -1 , nearly 2.5 times higher than those of a pure GO membrane, which is due to the improved binding affinity, great isosteric heat, and hydrogen bonds, while N 2 and CH 4 only show single-layer adsorption with solubility coefficients lower than 0.002 mmol·g -1 ·kPa -1 , and their weak adsorption is insusceptible to PDASA. Although acid gas diffusivity in GO channels is inhibited below 20 × 10 -6 cm 2 ·s -1 by PDASA, the solubility coefficient of acid gases is certainly high enough to ensure their separation efficiency. As a result, the permeabilities ( P ) of acid gases and their selectivities ( α ) over CH 4 are simultaneously improved ( P CO2 = 7265.5 Barrer, α CO2/CH4 = 95.7; P ( H2S+CO2) = 42075.1 Barrer, α H2S/CH4 = 243.8), which outperforms most of the ever-reported membranes. This theoretical study gives a mechanistic understanding of acid gas separation and provides a unique design strategy to develop high-performance GO membranes toward efficient natural gas processing.