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6-[( tert -Butyl-dimethyl-sil-yl)-oxy]-3-ethenyl-7-meth-oxy-4-[(tri-methyl-sil-yl)ethyn-yl]naphtho-[2,3- c ]furan-1(3 H )-one.

Matthias WeilThomas KremsmayrMarko D Mihovilovic
Published in: IUCrData (2020)
The tricyclic core in the title compound, C 26 H 34 O 4 Si 2 , shows disorder of the furan ring and deviates slightly from planarity, with the largest displacement from the least-squares plane [0.166 (2) Å] for the major disordered part of the methine C atom. To this C atom the likewise disordered vinyl group is attached, lying nearly perpendicular to the tricyclic core. In the crystal, mutual C-H⋯π inter-actions between the methine group of the furan ring and the central ring of the tricyclic core of an adjacent mol-ecule lead to inversion-related dimers.
Keyphrases
  • molecular dynamics
  • computed tomography
  • electron transfer
  • ionic liquid