Syntheses of Covalent Organic Frameworks via a One-Pot Suzuki Coupling and Schiff's Base Reaction for C 2 H 4 /C 3 H 6 Separation.

Covalent organic frameworks (COFs) featuring permanent porosity, designable topologies, and tailorable functionalities have attracted great interest in the past two decades. Developing efficient modular approaches to rationally constructing COFs from a set of molecules via covalent linking has been long pursued. Herein, we report a facile one-pot strategy to prepare COFs via an irreversible Suzuki coupling reaction followed by a reversible Schiff's base reaction without the need for intermediate isolation. Gram-scale ordered frameworks with kgm topology and rich porosities can be obtained by using diamino-aryl halide and dialdehyde aryl-borate compounds as monomers. The resultant microporous CR-COFs were used for efficient C 2 H 4 /C 3 H 6 separation. This strategy reduces the waste generated and efforts consumed by stepwise reactions and relative purification processes, making the large-scale syntheses of stable COFs feasible. Moreover, it offers a novel modular approach to designing COF materials.